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Effects of Zeolites X and Y on the Degradation of Malathion in Water

Published: 2 April 2013
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Abstract

The inclusion of both zeolites X and zeolite Y significantly affected the dissipation of malathion in water. In the fresh water, malathion degradation followed a pseudo-first order kinetics with concomitant half-life dropping from 8.76 hours in fresh water to 4.44 and 6.65 hours up on the introduction of faujasite X and Y, respectively. Zeolite X had higher degradation efficiency as compared to the Y type. In pure fresh water, Malathion mainly hydrolyzed to form malathion monocarboxylic and dicarboxylic acids as the only degradation products. However, in the presence of zeolites X and Y, in addition to the degradation products obtained in the fresh water, dimethyldithiophosphate was also formed. Notably, all the degradation products obtained are environmentally benign compared to the parent malathion. Eventually, both the adsorption on the zeolite framework and zeolite catalyzed degradation processes contributed to the overall dissipation behavior of the malathion and its degradation products.

Published in Science Journal of Chemistry (Volume 1, Issue 1)
DOI 10.11648/j.sjc.20130101.12
Page(s) 7-13
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Degradation Kinetics, Faujasite X And Y, Fresh Water, Half Life, Malathion

References
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[3] Newhart, K. 2006. Environmental fate of Malathion. Envi-ronmental monitoring branch, department of pesticide regu-lation. California Environmental Protection Agency. CA. USA.
[4] Neal, R. McCool, P. Younglove, T. 1993. Assessment of malathion and malaoxon concentration and persistence in water, sand, soil and plant matrices under controlled exposure conditions. California department of pesticide regulation. Environmental hazards assessment program. University of California, Riverside, CA. USA.
[5] Banerji, S.K. 1999. Environmental chemistry, 2nd Ed. Pren-tice-Hall of India, New Delhi, India.
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[7] Yang, S.W. Doetschman, D.C. Schulte, J.T. Sambur, J.B. Kanyi, C.W. Fox, J.D. Kowenje, C.O, Jones, B.R. Shema, N.D. 2006. Sodium X-Type faujasite zeolite decomposition of Dimethyl methylphosphonate(DMMP) to methylphosphonate. Nucleophilic zeolite reactions I. Microporous and mesoporous mater. 92, 56-60.
[8] Kanan, S.M. Kanan, M.C. Patterson, H.H. 2006. Silver na-noclusters doped in X and mordenite zeolites as heterogeneous catalysts for the decomposition of carbamate pesticides in solution. Res. Chem. Intermed. 32(9), 871-885.
[9] Satterfield, C.N. 1980. Heterogenous catalysis in practice. McGraw-Hill, New York. pp 301-308.
[10] Zweig, G. Devine, J.M. 1969. Determination of organo-phosphorus pesticide in water. Residue Rev. 26, 17-36.
[11] Zheng, Y. Hwang, H.M. 2006. Effects of temperature and microorganisms on Malathion transformation in river water. Bull. Environ. Contam. Toxicol. 76(4): 712-719.
[12] Wang, T.C. Hoffman, M.E. 1991. Degrada-tion of organophosphorus pesticides in coastal water. J. Assoc. Off. Anal. Chem. 74, 883−886.
[13] Freed, V.H. Chiou, C.T. Schmedding, D.W. 1979. Degradation of selected pesticide in water and soil. J. Agric. Food Chem. 27(4): 706-708.
[14] Mortier, W.J. Costenoble, M.L. Uytterhoeven, J.B. 1973. Location of cations in synthetic zeolite X and Y, III. Potas-sium-alkylammonium Y zeolites. J. phy. Chem. 77(24): 2880-2885.
[15] Teeter, D. 1988. Malathion (AC 6, 601): Hydrolysis. American Cyanamid Company study: PD-M25-59. Cheminova report No.12FYF summary. Wayne, NJ, USA.
[16] Howard, P.H. 1991. Handbook of environmental fate and exposure data for organic.
[17] House, J. E. 1997. Principles of Chemical Kinetics, Wm. C. Brown Publishers. Chicago, USA, pp 40-45.
[18] Mehlhorn, H. Armstrong, P.E. 2001. Encyclopedic reference of parasitology: disease, treatment and therapy. 2nd edition. Springer-verlag, Berlin. pp 674-678.
[19] Kanyi, C.W. Doetschman, D.C. Schulte, J.T. Yan, K. Wilson, R.E. Jones, B.R. Kowenje, C. O. 2006. Linear, primary mo-noalkanes chemistry in NaX and NaY faujasite zeolite with and without Na0-treatment. Zeolite as nucleophilic reagents II. Microporous and Mesoporous Mater., 92, 292-299.
[20] Kowenje, C.O. Jones, B.R. Doetschman, D.C. Yang, S-W. Schulte, J. DeCoste, J. Kanyi, C. W. 2010. Effects of copper exchange levels on complexation of ammonia in Cu (II)-exchanged X zeolites. S. Afr. J. Chem., 63, 6-10
Cite This Article
  • APA Style

    Joanne Atieno Ogunah, Chrispin Ounga Kowenje, Elly Tetty Osewe, Joseph Owour Lalah, David Agoro Jaoko, et al. (2013). Effects of Zeolites X and Y on the Degradation of Malathion in Water. Science Journal of Chemistry, 1(1), 7-13. https://doi.org/10.11648/j.sjc.20130101.12

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    ACS Style

    Joanne Atieno Ogunah; Chrispin Ounga Kowenje; Elly Tetty Osewe; Joseph Owour Lalah; David Agoro Jaoko, et al. Effects of Zeolites X and Y on the Degradation of Malathion in Water. Sci. J. Chem. 2013, 1(1), 7-13. doi: 10.11648/j.sjc.20130101.12

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    AMA Style

    Joanne Atieno Ogunah, Chrispin Ounga Kowenje, Elly Tetty Osewe, Joseph Owour Lalah, David Agoro Jaoko, et al. Effects of Zeolites X and Y on the Degradation of Malathion in Water. Sci J Chem. 2013;1(1):7-13. doi: 10.11648/j.sjc.20130101.12

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  • @article{10.11648/j.sjc.20130101.12,
      author = {Joanne Atieno Ogunah and Chrispin Ounga Kowenje and Elly Tetty Osewe and Joseph Owour Lalah and David Agoro Jaoko and Robert Njuguna Koigi},
      title = {Effects of Zeolites X and Y on the Degradation of Malathion in Water},
      journal = {Science Journal of Chemistry},
      volume = {1},
      number = {1},
      pages = {7-13},
      doi = {10.11648/j.sjc.20130101.12},
      url = {https://doi.org/10.11648/j.sjc.20130101.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130101.12},
      abstract = {The inclusion of both zeolites X and zeolite Y significantly affected the dissipation of malathion in water. In the fresh water, malathion degradation followed a pseudo-first order kinetics with concomitant half-life dropping from 8.76 hours in fresh water to 4.44 and 6.65 hours up on the introduction of faujasite X and Y, respectively. Zeolite X had higher degradation efficiency as compared to the Y type. In pure fresh water, Malathion mainly hydrolyzed to form malathion monocarboxylic and dicarboxylic acids as the only degradation products. However, in the presence of zeolites X and Y, in addition to the degradation products obtained in the fresh water, dimethyldithiophosphate was also formed. Notably, all the degradation products obtained are environmentally benign compared to the parent malathion. Eventually, both the adsorption on the zeolite framework and zeolite catalyzed degradation processes contributed to the overall dissipation behavior of the malathion and its degradation products.},
     year = {2013}
    }
    

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  • TY  - JOUR
    T1  - Effects of Zeolites X and Y on the Degradation of Malathion in Water
    AU  - Joanne Atieno Ogunah
    AU  - Chrispin Ounga Kowenje
    AU  - Elly Tetty Osewe
    AU  - Joseph Owour Lalah
    AU  - David Agoro Jaoko
    AU  - Robert Njuguna Koigi
    Y1  - 2013/04/02
    PY  - 2013
    N1  - https://doi.org/10.11648/j.sjc.20130101.12
    DO  - 10.11648/j.sjc.20130101.12
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 7
    EP  - 13
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20130101.12
    AB  - The inclusion of both zeolites X and zeolite Y significantly affected the dissipation of malathion in water. In the fresh water, malathion degradation followed a pseudo-first order kinetics with concomitant half-life dropping from 8.76 hours in fresh water to 4.44 and 6.65 hours up on the introduction of faujasite X and Y, respectively. Zeolite X had higher degradation efficiency as compared to the Y type. In pure fresh water, Malathion mainly hydrolyzed to form malathion monocarboxylic and dicarboxylic acids as the only degradation products. However, in the presence of zeolites X and Y, in addition to the degradation products obtained in the fresh water, dimethyldithiophosphate was also formed. Notably, all the degradation products obtained are environmentally benign compared to the parent malathion. Eventually, both the adsorption on the zeolite framework and zeolite catalyzed degradation processes contributed to the overall dissipation behavior of the malathion and its degradation products.
    VL  - 1
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemistry, Maseno University, P. O. Box 333-40105, Maseno, Kenya

  • Department of Chemistry, Maseno University, P. O. Box 333-40105, Maseno, Kenya

  • Kisumu Polytechnic P. O. Box 143-40100, Kisumu, Kenya

  • Department of Chemical Sciences and Technology, Technical University of Kenya, P. O. Box 52428-00200, Nairobi, Kenya

  • Department of Chemistry, Maseno University, P. O. Box 333-40105, Maseno, Kenya

  • Kenya Plant Health Inspectorate Service, P. O. Box 49592-00100 Nairobi, Kenya

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