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Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions

Received: 13 June 2022     Accepted: 29 June 2022     Published: 12 July 2022
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Abstract

The occurrence of heavy metals in water constitute a major threat to both humans and aquatic animals. The current research work investigated the adsorptive behavior of a natural clay obtained from Goronyo Local Government, Sokoto state, Nigeria for Pb(II) and Cd(II) ions removal from aqueous solution. The clay sample was characterized using different techniques (X-ray fluorescence, X-ray diffraction, and Fourier transform infrared spectroscopy). Batch adsorption method was employed at room temperature to investigate the amount of metal ion adsorbed per gram of clay as a function of solution pH, contact time, adsorbent dosage and metal ion concentration. Optimum adsorption was attained at solution pH of 5.5 and 6 for Pb(II) and Cd(II) ions, respectively, contact time of 60 min, adsorbent dosage of 0.5 g/50 mL and metal ion concentration of 50 mg/L. Kinetic analysis revealed that the adsorption conform to pseudo-second order kinetic model. Among the different isotherms tested, the Freundlich and Langmuir isotherms gave the best fit, illustrating that the interaction was predominantly chemical in nature but the adsorption sites were heterogeneous. The maximum adsorption amount per gram of the clay adsorbent was found to be 49.72 and 31.63 mg/g for Pb(II) and Cd (II) ions, respectively. These results suggest that GN clay can be efficiently utilized as a low-cost adsorbent for metal ions removal from aqueous systems.

Published in Science Journal of Chemistry (Volume 10, Issue 4)
DOI 10.11648/j.sjc.20221004.11
Page(s) 93-102
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Adsorption, Clay, Heavy Metals, Kinetics, Adsorption Isotherm

References
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Cite This Article
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    Aminu Koko Rabiu, Murtala Maidamma Ambursa, Yakubu Yahaya, Faruk Umar Maiahu, Farooq Abubakar Atiku. (2022). Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions. Science Journal of Chemistry, 10(4), 93-102. https://doi.org/10.11648/j.sjc.20221004.11

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    ACS Style

    Aminu Koko Rabiu; Murtala Maidamma Ambursa; Yakubu Yahaya; Faruk Umar Maiahu; Farooq Abubakar Atiku. Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions. Sci. J. Chem. 2022, 10(4), 93-102. doi: 10.11648/j.sjc.20221004.11

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    AMA Style

    Aminu Koko Rabiu, Murtala Maidamma Ambursa, Yakubu Yahaya, Faruk Umar Maiahu, Farooq Abubakar Atiku. Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions. Sci J Chem. 2022;10(4):93-102. doi: 10.11648/j.sjc.20221004.11

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  • @article{10.11648/j.sjc.20221004.11,
      author = {Aminu Koko Rabiu and Murtala Maidamma Ambursa and Yakubu Yahaya and Faruk Umar Maiahu and Farooq Abubakar Atiku},
      title = {Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions},
      journal = {Science Journal of Chemistry},
      volume = {10},
      number = {4},
      pages = {93-102},
      doi = {10.11648/j.sjc.20221004.11},
      url = {https://doi.org/10.11648/j.sjc.20221004.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20221004.11},
      abstract = {The occurrence of heavy metals in water constitute a major threat to both humans and aquatic animals. The current research work investigated the adsorptive behavior of a natural clay obtained from Goronyo Local Government, Sokoto state, Nigeria for Pb(II) and Cd(II) ions removal from aqueous solution. The clay sample was characterized using different techniques (X-ray fluorescence, X-ray diffraction, and Fourier transform infrared spectroscopy). Batch adsorption method was employed at room temperature to investigate the amount of metal ion adsorbed per gram of clay as a function of solution pH, contact time, adsorbent dosage and metal ion concentration. Optimum adsorption was attained at solution pH of 5.5 and 6 for Pb(II) and Cd(II) ions, respectively, contact time of 60 min, adsorbent dosage of 0.5 g/50 mL and metal ion concentration of 50 mg/L. Kinetic analysis revealed that the adsorption conform to pseudo-second order kinetic model. Among the different isotherms tested, the Freundlich and Langmuir isotherms gave the best fit, illustrating that the interaction was predominantly chemical in nature but the adsorption sites were heterogeneous. The maximum adsorption amount per gram of the clay adsorbent was found to be 49.72 and 31.63 mg/g for Pb(II) and Cd (II) ions, respectively. These results suggest that GN clay can be efficiently utilized as a low-cost adsorbent for metal ions removal from aqueous systems.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Adsorptive Behaviour of a Nigerian Natural Clay for the Removal of Lead and Cadmium from Aqueous Solutions
    AU  - Aminu Koko Rabiu
    AU  - Murtala Maidamma Ambursa
    AU  - Yakubu Yahaya
    AU  - Faruk Umar Maiahu
    AU  - Farooq Abubakar Atiku
    Y1  - 2022/07/12
    PY  - 2022
    N1  - https://doi.org/10.11648/j.sjc.20221004.11
    DO  - 10.11648/j.sjc.20221004.11
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 93
    EP  - 102
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20221004.11
    AB  - The occurrence of heavy metals in water constitute a major threat to both humans and aquatic animals. The current research work investigated the adsorptive behavior of a natural clay obtained from Goronyo Local Government, Sokoto state, Nigeria for Pb(II) and Cd(II) ions removal from aqueous solution. The clay sample was characterized using different techniques (X-ray fluorescence, X-ray diffraction, and Fourier transform infrared spectroscopy). Batch adsorption method was employed at room temperature to investigate the amount of metal ion adsorbed per gram of clay as a function of solution pH, contact time, adsorbent dosage and metal ion concentration. Optimum adsorption was attained at solution pH of 5.5 and 6 for Pb(II) and Cd(II) ions, respectively, contact time of 60 min, adsorbent dosage of 0.5 g/50 mL and metal ion concentration of 50 mg/L. Kinetic analysis revealed that the adsorption conform to pseudo-second order kinetic model. Among the different isotherms tested, the Freundlich and Langmuir isotherms gave the best fit, illustrating that the interaction was predominantly chemical in nature but the adsorption sites were heterogeneous. The maximum adsorption amount per gram of the clay adsorbent was found to be 49.72 and 31.63 mg/g for Pb(II) and Cd (II) ions, respectively. These results suggest that GN clay can be efficiently utilized as a low-cost adsorbent for metal ions removal from aqueous systems.
    VL  - 10
    IS  - 4
    ER  - 

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Author Information
  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

  • Department of Pure and Applied Chemistry, Kebbi State University of Science and Technology, Aliero, Nigeria

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