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Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater

Received: 20 April 2021     Accepted: 20 May 2021     Published: 29 June 2021
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Abstract

Polysiloxanes are characterized by silicon and oxygen backbone and are hydrophobic in nature with low moisture uptake widely used for medical applications. Polysiloxane immobilized thiosalicylic acid ligand system has been prepared through sol-gel method, gelation was observed after 40 minutes. The immobilized ligand was characterized using FTIR, the spectrum showed characteristic absorption bands (cm-1) at: 3377 (OH), 2981 (C-H stretch); 2631 (SH); 1587 to 1684 (C=C, C=O); 1032 to 1144 (Si - O) respectively. SEM analysis showed irregular particle sizes of the polysiloxane matrices while EDX elemental composition gave (wt %): 3-CPPS; Si (50.45), O (25.02) and Cl (24.57). F - 3CPPS showed, O (58.68), Si (41.32); thiosalicylic (7.14 of S). The extraction of metal ions (Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+) were studied using Microwave Plasma Atomic Emission Spectrophotometer (Agilent MPAES-4200) at pH 6.0. Thermodynamic range with respect to Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+ yielded negative values forΔGo: Cu2+-(11.483 to 14.842) to Zn2+ -(14.368 to 14.842)KJmol-1; positive values for ΔHo: Fe3+ (0.000) to Pb2+ (105.130)KJmol-1 and ΔSo: Zn2+ (47.421) to Pb2+ (389.328)Jmol1K1 respectively, indicating spontaneous, endothermic reactions and high degree of disorderliness with respect to metal ion binding capacity to the ligand system.

Published in Science Journal of Chemistry (Volume 9, Issue 3)
DOI 10.11648/j.sjc.20210903.13
Page(s) 72-79
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Tannery Wastewater, Detoxification, Polysiloxane, Nanomers, Thiosalicylic Ligand

References
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    Bulus Habila, Emmanuel Chidiebere Ezeh, Simon Moses Saidu, John Chidozie Attah, Paul Okechukwu Nsude, et al. (2021). Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater. Science Journal of Chemistry, 9(3), 72-79. https://doi.org/10.11648/j.sjc.20210903.13

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    ACS Style

    Bulus Habila; Emmanuel Chidiebere Ezeh; Simon Moses Saidu; John Chidozie Attah; Paul Okechukwu Nsude, et al. Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater. Sci. J. Chem. 2021, 9(3), 72-79. doi: 10.11648/j.sjc.20210903.13

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    AMA Style

    Bulus Habila, Emmanuel Chidiebere Ezeh, Simon Moses Saidu, John Chidozie Attah, Paul Okechukwu Nsude, et al. Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater. Sci J Chem. 2021;9(3):72-79. doi: 10.11648/j.sjc.20210903.13

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  • @article{10.11648/j.sjc.20210903.13,
      author = {Bulus Habila and Emmanuel Chidiebere Ezeh and Simon Moses Saidu and John Chidozie Attah and Paul Okechukwu Nsude and Emmanuel Agboeze and Ike Christian Ozoemena and Jonathan Danladi Gaiya and Tachye Ninnat Bwankhot Shekarri and Sunday Ture Dahiru and Olajide Joseph Igbehinadun},
      title = {Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater},
      journal = {Science Journal of Chemistry},
      volume = {9},
      number = {3},
      pages = {72-79},
      doi = {10.11648/j.sjc.20210903.13},
      url = {https://doi.org/10.11648/j.sjc.20210903.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20210903.13},
      abstract = {Polysiloxanes are characterized by silicon and oxygen backbone and are hydrophobic in nature with low moisture uptake widely used for medical applications. Polysiloxane immobilized thiosalicylic acid ligand system has been prepared through sol-gel method, gelation was observed after 40 minutes. The immobilized ligand was characterized using FTIR, the spectrum showed characteristic absorption bands (cm-1) at: 3377 (OH), 2981 (C-H stretch); 2631 (SH); 1587 to 1684 (C=C, C=O); 1032 to 1144 (Si - O) respectively. SEM analysis showed irregular particle sizes of the polysiloxane matrices while EDX elemental composition gave (wt %): 3-CPPS; Si (50.45), O (25.02) and Cl (24.57). F - 3CPPS showed, O (58.68), Si (41.32); thiosalicylic (7.14 of S). The extraction of metal ions (Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+) were studied using Microwave Plasma Atomic Emission Spectrophotometer (Agilent MPAES-4200) at pH 6.0. Thermodynamic range with respect to Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+ yielded negative values forΔGo: Cu2+-(11.483 to 14.842) to Zn2+ -(14.368 to 14.842)KJmol-1; positive values for ΔHo: Fe3+ (0.000) to Pb2+ (105.130)KJmol-1 and ΔSo: Zn2+ (47.421) to Pb2+ (389.328)Jmol1K1 respectively, indicating spontaneous, endothermic reactions and high degree of disorderliness with respect to metal ion binding capacity to the ligand system.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Immobilized Thiosalicylic Ligand System Potentials for the Detoxification of Some Heavy Metals from Tannery Wastewater
    AU  - Bulus Habila
    AU  - Emmanuel Chidiebere Ezeh
    AU  - Simon Moses Saidu
    AU  - John Chidozie Attah
    AU  - Paul Okechukwu Nsude
    AU  - Emmanuel Agboeze
    AU  - Ike Christian Ozoemena
    AU  - Jonathan Danladi Gaiya
    AU  - Tachye Ninnat Bwankhot Shekarri
    AU  - Sunday Ture Dahiru
    AU  - Olajide Joseph Igbehinadun
    Y1  - 2021/06/29
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sjc.20210903.13
    DO  - 10.11648/j.sjc.20210903.13
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 72
    EP  - 79
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20210903.13
    AB  - Polysiloxanes are characterized by silicon and oxygen backbone and are hydrophobic in nature with low moisture uptake widely used for medical applications. Polysiloxane immobilized thiosalicylic acid ligand system has been prepared through sol-gel method, gelation was observed after 40 minutes. The immobilized ligand was characterized using FTIR, the spectrum showed characteristic absorption bands (cm-1) at: 3377 (OH), 2981 (C-H stretch); 2631 (SH); 1587 to 1684 (C=C, C=O); 1032 to 1144 (Si - O) respectively. SEM analysis showed irregular particle sizes of the polysiloxane matrices while EDX elemental composition gave (wt %): 3-CPPS; Si (50.45), O (25.02) and Cl (24.57). F - 3CPPS showed, O (58.68), Si (41.32); thiosalicylic (7.14 of S). The extraction of metal ions (Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+) were studied using Microwave Plasma Atomic Emission Spectrophotometer (Agilent MPAES-4200) at pH 6.0. Thermodynamic range with respect to Cr3+, Fe3+, Pb2+, Cu2+ and Zn2+ yielded negative values forΔGo: Cu2+-(11.483 to 14.842) to Zn2+ -(14.368 to 14.842)KJmol-1; positive values for ΔHo: Fe3+ (0.000) to Pb2+ (105.130)KJmol-1 and ΔSo: Zn2+ (47.421) to Pb2+ (389.328)Jmol1K1 respectively, indicating spontaneous, endothermic reactions and high degree of disorderliness with respect to metal ion binding capacity to the ligand system.
    VL  - 9
    IS  - 3
    ER  - 

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Author Information
  • Department of Leather and Leather Products/Polymer, Nigerian Institute of Leather and Science Technology, Zaria, Nigeria

  • Department of Pure and Industrial Chemistry, Enugu State University of Science and Technology, Enugu, Nigeria

  • National Institute of Hospitality and Tourism, Kaduna Campus, Kaduna, Nigeria

  • Department of Pure and Industrial Chemistry, Enugu State University of Science and Technology, Enugu, Nigeria

  • Department of Pure and Industrial Chemistry, Enugu State University of Science and Technology, Enugu, Nigeria

  • Department of Pure and Industrial Chemistry, Enugu State University of Science and Technology, Enugu, Nigeria

  • Department of Pure and Industrial Chemistry, Enugu State University of Science and Technology, Enugu, Nigeria

  • Department of Leather and Leather Products/Polymer, Nigerian Institute of Leather and Science Technology, Zaria, Nigeria

  • Department of Leather and Leather Products/Polymer, Nigerian Institute of Leather and Science Technology, Zaria, Nigeria

  • Department of Leather and Leather Products/Polymer, Nigerian Institute of Leather and Science Technology, Zaria, Nigeria

  • Department of Leather and Leather Products/Polymer, Nigerian Institute of Leather and Science Technology, Zaria, Nigeria

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