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Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base

Received: 9 September 2020     Accepted: 23 September 2020     Published: 29 September 2020
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Abstract

Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.

Published in Science Journal of Chemistry (Volume 8, Issue 5)
DOI 10.11648/j.sjc.20200805.13
Page(s) 113-118
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Zinc, Metalloligand, o-vanillin, 1, 2-diaminobenzene

References
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    Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. (2020). Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Science Journal of Chemistry, 8(5), 113-118. https://doi.org/10.11648/j.sjc.20200805.13

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    ACS Style

    Pokpa Haba; Mouhamadou Moustapha Sow; Mamour Sarr; Ibrahima Elhadji Thiam; Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci. J. Chem. 2020, 8(5), 113-118. doi: 10.11648/j.sjc.20200805.13

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    AMA Style

    Pokpa Haba, Mouhamadou Moustapha Sow, Mamour Sarr, Ibrahima Elhadji Thiam, Mahy Diaw, et al. Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base. Sci J Chem. 2020;8(5):113-118. doi: 10.11648/j.sjc.20200805.13

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  • @article{10.11648/j.sjc.20200805.13,
      author = {Pokpa Haba and Mouhamadou Moustapha Sow and Mamour Sarr and Ibrahima Elhadji Thiam and Mahy Diaw and Pascal Retailleau and Mohamed Lamine Gaye},
      title = {Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base},
      journal = {Science Journal of Chemistry},
      volume = {8},
      number = {5},
      pages = {113-118},
      doi = {10.11648/j.sjc.20200805.13},
      url = {https://doi.org/10.11648/j.sjc.20200805.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20200805.13},
      abstract = {Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Syntheses, Characterization, and X-ray Crystal Structure of Heteronuclear Zn/Na Assembled with Salen-type Schiff Base
    AU  - Pokpa Haba
    AU  - Mouhamadou Moustapha Sow
    AU  - Mamour Sarr
    AU  - Ibrahima Elhadji Thiam
    AU  - Mahy Diaw
    AU  - Pascal Retailleau
    AU  - Mohamed Lamine Gaye
    Y1  - 2020/09/29
    PY  - 2020
    N1  - https://doi.org/10.11648/j.sjc.20200805.13
    DO  - 10.11648/j.sjc.20200805.13
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 113
    EP  - 118
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.20200805.13
    AB  - Herein we reported the crystal structure of a dinuclear complex [{ZnIINaI (L)(EtOH)(NO3)]}] (2) obtained by reaction with the metalloligand [Zn(L)].(H2O) (1) and sodium nitrate. The metalloligand (1) and the dinuclear (2) complexes are characterized by IR and physical measurement. Spectroscopic evidence indicated that the Schiff base H2L behave an N2O2O’ 2 coordination tetradentate ligand. Suitable crystals of the compound 2 were grown by slow evaporation of ethanol solution for two weeks. The structure of 2 was elucidated by X-ray diffraction analysis. The compound crystallizes in the monoclinic crystal system with a space group of P21/c. The asymmetric unit of the compound contains one dideprotonated ligand molecule, on tetracoordinated zinc (II) ion, one heptacoordinated sodium(I) ion, one bidentate nitrate group and one coordinated ethanol molecule resulting in a structure formulated as [Zn(µ-L)Na(NO3)(EtOH)]. In the structure the ZnII ion is tetracoordinated and the environment around the zinc (II) is best described as a planar square geometry. The NaI ion is seven-coordinated in a severely distorted bipyramid pentagon environment. The interplanar angles between the two phenyl rings with a methoxy substituent is 4.208 (4)°, while the dihedral angle values of these groups with the phenyl carrying amino groups are respectively 7.499 (5)° and 11.594 (5)°. The Zn–Na distance is 3.4244 (9) Å. In the crystal structure numerous intramolecular and intermolecular hydrogen bonds link the molecules in a three-dimensional network.
    VL  - 8
    IS  - 5
    ER  - 

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Author Information
  • Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

  • Department of Chemistry, University Alioune Diop, Bambey, Senegal

  • Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

  • Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

  • Department of Chemistry, University Alioune Diop, Bambey, Senegal

  • Natural Substances Laboratory, University Paris-Sud, Gif-sur-Yvette, France

  • Department of Chemistry, University Cheikh Anta Diop, Dakar, Senegal

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