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Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline

Received: 16 May 2013     Published: 20 June 2013
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Abstract

This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.

Published in Science Journal of Chemistry (Volume 1, Issue 2)
DOI 10.11648/j.sjc.20130102.12
Page(s) 21-25
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Stability constants, 8-Hydroxyquinoline, Sc(III), Y(III), La(III)

References
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  • APA Style

    Naciye Türkel. (2013). Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Science Journal of Chemistry, 1(2), 21-25. https://doi.org/10.11648/j.sjc.20130102.12

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    ACS Style

    Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci. J. Chem. 2013, 1(2), 21-25. doi: 10.11648/j.sjc.20130102.12

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    AMA Style

    Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci J Chem. 2013;1(2):21-25. doi: 10.11648/j.sjc.20130102.12

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  • @article{10.11648/j.sjc.20130102.12,
      author = {Naciye Türkel},
      title = {Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline},
      journal = {Science Journal of Chemistry},
      volume = {1},
      number = {2},
      pages = {21-25},
      doi = {10.11648/j.sjc.20130102.12},
      url = {https://doi.org/10.11648/j.sjc.20130102.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130102.12},
      abstract = {This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.},
     year = {2013}
    }
    

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    T1  - Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline
    AU  - Naciye Türkel
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    N1  - https://doi.org/10.11648/j.sjc.20130102.12
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    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
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    UR  - https://doi.org/10.11648/j.sjc.20130102.12
    AB  - This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.
    VL  - 1
    IS  - 2
    ER  - 

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Author Information
  • Uluda? University, Faculty of Arts and Sciences, Department of Chemistry, 16059-Bursa, Turkey

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